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Recent studies have indicated that substitutes for conventional petroleum resources will be needed to meet U.S. transportation energy demand in the first half of this century. One possible substitute is natural gas, which can be used as a transportation fuel directly in compressed natural gas or liquefied natural gas vehicles or as resource fuel for the production of hydrogen for fuel cell vehicles. This paper contains a preliminary assessment of the availability of U.S. natural gas resources to meet future U.S. transportation fuel demand. Several scenarios of natural gas demand, including transportation demand, in the United States to 2050 are developed. Natural gas resource estimates for the United States are discussed. Potential Canadian and Mexican exports to the United States are estimated. Two scenarios of potential imports from outside North America are also developed.

Süd-Chemie Inc. is producing and supplying an autothermal reforming (ATR) catalyst that was developed by Argonne National Laboratory (ANL) for reforming hydrocarbon fuels to generate H2 for automotive fuel cell systems. The catalyst is derived from solid oxide fuel cell technology, where a transition metal is supported on an oxide-ion-conducting substrate, such as ceria or zirconia, that is doped with an un-reducible oxide, such as gadolinium or samarium, to improve its oxide ion conductivity and to increase the number of surface oxygen ion vacancies. The catalyst has been shown to produce an H2-rich gas (reformate) from a wide variety of hydrocarbon fuels, including methane, natural gas, and commercial-grade gasolines and diesels with high selectivity. Platinum was the transition metal used in the first generation of the ANL catalyst.

This paper analyzes four recent major studies carried out by MIT, a GM-led team, Directed Technologies, Inc., and A. D. Little, Inc. to assess advanced technology vehicles. These analyses appear to differ greatly concerning their perception of the energy benefits of advanced technology vehicles, leading to great uncertainties in estimating full-fuel-cycle (or “well-to-wheel”) greenhouse gas (GHG) emission reduction potentials and/or fuel feedstock requirements per mile of service. Advanced vehicles include, but are not limited to, advanced gasoline and diesel internal combustion engine (ICE) vehicles, hybrid electric vehicles (HEVs) with gasoline, diesel, and compressed natural gas (CNG) ICEs, and various kinds of fuel-cell based vehicles (FCVs), such as direct hydrogen FCVs and gasoline or methanol fuel-based FCVs.

The high octane rating and more plentiful domestic supply of natural gas make it an excellent alternative to gasoline. Recent studies have shown that using natural gas in dual fuel engines provides one possible strategy for leveraging the advantages of both natural gas and gasoline. In particular, such engines been able to improve overall engine efficiencies and load capacity when they leverage direct injection of the natural gas fuel. While the benefits of these engine concepts are still being explored, differences in fuel composition, combustion process and in-cylinder mixing could lead to dramatically different emissions which can substantially impact the effectiveness of the engine’s exhaust aftertreatment system. In order to explore this topic, this study examined the variations in speciated hydrocarbon emissions which occur for different fuel blends of E10 and compressed natural gas and for different fuel injection strategies on a spark-ignition engine.

Heat loss through wall boundaries play a dominant role in the overall performance and efficiency of internal combustion engines. Typical engine simulations use constant temperature wall boundary conditions [1, 2, 3]. These boundary conditions cannot be estimated accurately from experiments due to the complexities involved with engine combustion. As a result, they introduce a large uncertainty in engine simulations and serve as a tuning parameter. Modeling the process of heat transfer through the solid walls in an unsteady engine computational fluid dynamics (CFD) simulation can lead to the development of higher fidelity engine models. These models can be used to study the impact of heat loss on engine efficiency and explore new design methodologies that can reduce heat losses. In this work, a single cylinder diesel engine is modeled along with the solid piston coupled to the fluid domain.

This study examines the dynamics and control of an engine operated with late intake valve closure (LIVC) timings in a dual-fuel combustion mode. The engine features a fuel delivery system in which diesel is direct-injected and natural gas is port-injected. Despite the benefits of LIVC and dual-fuel strategy, combining these two techniques resulted in efficiency losses due to the variability of the combustion process across cylinders. The difference in power production across cylinders ranges from 9% at an IVC of 570°ATDC* to 38% at an IVC of 620 °ATDC and indicates an increasingly uneven fuel distribution as the intake valve remains open longer in the compression stroke. This paper describes an approach for controlling the amount of fuel injected into each cylinders’ port of an inline six- cylinder heavy-duty dual-fuel engine to minimize the variations in fuel distribution across cylinder.

Using natural gas in an internal combustion engine (ICE) is emerging as a promising way to improve thermal efficiency and reduce exhaust emissions. In the development of such engine platforms, computational fluid dynamics (CFD) plays a fundamental role in the optimization of geometries and operating parameters. One of the most relevant issues in the simulation of direct injection (DI) gaseous processes is the accurate prediction of the gas jet evolution. The simulation of the injection process for a gaseous fuel does not require complex modeling, nevertheless properly describing high-pressure gas jets remains a challenging task. At the exit of the nozzle, the injected gas is under-expanded, the flow becomes supersonic and shocks occur due to compressibility effects. These phenomena lead to challenging computational requirements resulting from high grid resolution and low computational time-steps.

A heavy-duty vehicle (HDV) module of the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREETTM) model has been developed at Argonne National Laboratory. The fuel-cycle GREET model has been published extensively and contains data on fuel-cycles and vehicle operation of light-duty vehicles. The addition of the HDV module to the GREET model allows for well-to-wheel (WTW) analyses of heavy-duty advanced technology and alternative fuel vehicles (AFVs), which has been lacking in the literature. WTW analyses of HDVs becomes increasingly important to understand the fuel consumption and greenhouse gas (GHG) emissions impacts of newly enacted and future HDV regulations from the Environmental Protection Agency and the Department of Transportation’s National Highway Traffic Safety Administration.

This paper presents the validation of an entire vehicle model of the Honda Accord Plug-in Hybrid Electric Vehicle (PHEV), which has a new powertrain system that can be driven in both series and parallel hybrid drive using a clutch, including thermal aspects. The Accord PHEV is a series-parallel PHEV with about 21 km of all-electric range and no multi-speed gearbox. Vehicle testing was performed at Argonne’s Advanced Powertrain Research Facility on a chassis dynamometer set in a thermal chamber. First, components (engine, battery, motors and wheels) were modeled using the test data and publicly available assumptions. This includes calibration of the thermal aspects, such as engine efficiency as a function of coolant temperature. In the second phase, the vehicle-level control strategy, especially the energy management, was analyzed in normal conditions in both charge-depleting and charge-sustaining modes.

Natural Gas (NG) is an alternative fuel which has attracted a lot of attention recently, in particular in the US due to shale gas availability. The higher hydrogen-to-carbon (H/C) ratio, compared to gasoline, allows for decreasing carbon dioxide emissions throughout the entire engine map. Furthermore, the high knock resistance of NG allows increasing the efficiency at high engine loads compared to fuels with lower knock resistance. NG direct injection (DI) allows for fuel to be added after intake valve closing (IVC) resulting in an increase in power density compared to an injection before IVC. Steady-state engine tests were performed on a single-cylinder research engine equipped with gasoline (E10) port-fuel injection (PFI) and NG DI to allow for in-cylinder blending of both fuels. Knock investigations were performed at two discrete compression ratios (CR), 10.5 and 12.5.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

Their easy availability, lower well-to-wheel emissions, and relative ease of use with existing engine technologies have made ethanol and ethanol-gasoline blends a viable alternative to gasoline for use in spark-ignition (SI) engines. The lower energy density of ethanol and ethanol-gasoline blends, however, results in higher volumetric fuel consumption compared with gasoline. Also, the higher latent heat of vaporization can result in cold-start issues with higher-level ethanol blends. On the other hand, a higher octane number, which indicates resistance to knock and potentially enables more optimal combustion phasing, results in better engine efficiency, especially at higher loads. This paper compares the fuel consumption and emissions of two ethanol blends (E50 and E85) with those for gasoline when used in conventional (non-hybrid) and power-split-type plug-in hybrid electric vehicles (PHEVs).

With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).

Development of computationally fast, numerically robust, and physically accurate models to compute engine-out emissions can play an important role in the design, development, and optimization of automotive engines powered by alternative fuels (such as natural gas and H2) and fuel blends (such as ethanol-blended fuels and biodiesel-blended fuels). Detailed multidimensional models that couple fluid dynamics and chemical kinetics place stringent demands on the computational resources and time, precluding their use in design and parametric studies. This work describes the development of an integrated design tool that couples a fast, robust, physics-based, two-zone quasi-dimensional engine model with modified reaction-rate-controlled models to compute engine-out NO and CO for a wide variety of fuel-additive blends.

Lean operation of natural gas fired reciprocating engines has been the preferred mode of operation as it allows low NOx emissions and simultaneous high overall efficiencies. In such engines, the operation point is often close to where the ignition boundary and the knock limiting boundary cross-over. While knocking is, to a large extent, limited by engine design, ignition of lean-mixtures is limited by the mode of ignition. Since significant benefits can be achieved by extending the lean-ignition limits, many groups have been researching alternate ways to achieve ignition reliably. One of the methods, laser ignition, appears promising as it achieves ignition at high pressures and under lean conditions relatively easily. However, most of the current knowledge about laser ignition is based on measurements performed at room temperature. In this paper, ignition studies on methane-air mixtures under in-cylinder conditions are presented.

Validation of a vehicle simulation model of the Chevrolet Volt 2016 was conducted. The Chevrolet Volt 2016 is equipped with the new “Voltec” extended-range propulsion system introduced into the market in 2016. The second generation Volt powertrain system operates in five modes, including two electric vehicle modes and three extended-range modes. Model development and validation were conducted using the test data performed on the chassis dynamometer set in a thermal chamber of Argonne National Laboratory’s Advanced Powertrain Research Facility. First, the components of the vehicle, such as the engine, motor, battery, wheels, and chassis, were modeled, including thermal aspects based on the test data. For example, engine efficiency changes dependent on the coolant temperature, or chassis heating or air-conditioning operations according to the ambient and cabin temperature, were applied.

This study presents experimental and numerical examination of directly injected (DI) propane and iso-octane, surrogates for liquified petroleum gas (LPG) and gasoline, respectively, at various engine like conditions with the overall objective to establish the baseline with regards to fuel delivery required for future high efficiency DI-LPG fueled heavy-duty engines. Sprays for both iso-octane and propane were characterized and the results from the optical diagnostic techniques including high-speed Schlieren and planar Mie scattering imaging were applied to differentiate the liquid-phase regions and the bulk spray phenomenon from single plume behaviors. The experimental results, coupled with high-fidelity internal nozzle-flow simulations were then used to define best practices in CFD Lagrangian spray models.

Because of its abundance and because it offers significant energy and environmental advantages, natural gas has been promoted for use in motor vehicles. A number of transportation fuels are produced from natural gas; each is distinct in terms of upstream production activities and vehicle usage. In this paper, we present greenhouse gas emission impacts of using various natural gas–based transportation fuels. We include eight fuels – compressed natural gas, liquefied natural gas, liquefied petroleum gas, methanol, hydrogen, dimethyl ether, Fischer–Tropsch diesel, and electricity – for use in five types of motor vehicles – spark–ignition vehicles, compression–ignition vehicles, hybrid electric vehicles, battery–powered electric vehicles, and fuel–cell vehicles. In our evaluation, we separate these fuels and vehicle technologies into near– and long–term options to address technology progress over time.

The Prius is a major achievement by Toyota: it is the first mass-produced HEV with the first available HEV-optimized engine. Argonne National Laboratory's Advanced Powertrain Test Facility has been testing the Prius for model validation and technology performance and assessment. A significant part of the Prius test program is focused on testing and mapping the engine. A short-length torque sensor was installed in the powertrain in-situ. The torque sensor data allow insight into vehicle operational strategy, engine utilization, engine efficiency, and specific emissions. This paper describes the design and process necessary to install a torque sensor in a vehicle and shows the high-fidelity data measured during chassis dynamometer testing. The engine was found to have a maximum thermodynamic efficiency of 36.4%. Emissions and catalyst efficiency maps were also produced.

This paper presents the results of Argonne National Laboratory's assessment of the fuel-cycle energy and emissions impacts of 13 combinations of fuels and propulsion systems that are potential candidates for light-duty vehicles with tripled fuel economy (3X vehicles). These vehicles are being developed by the Partnership for a New Generation of Vehicles (PNGV). Eleven fuels were considered: reformulated gasoline (RFG), reformulated diesel (RFD), methanol, ethanol, dimethyl ether, liquefied petroleum gas (LPG), compressed natural gas (CNG), liquefied natural gas (LNG), biodiesel, Fischer-Tropsch diesel and hydrogen. RFG, methanol, ethanol, LPG, CNG and LNG were assumed to be burned in spark-ignition, direct-injection (SIDI) engines. RFD, Fischer-Tropsch diesel, biodiesel and dimethyl ether were assumed to be burned in compression-ignition, direct-injection (CIDI) engines. Hydrogen, RFG and methanol were assumed to be used in fuel-cell vehicles.